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Titanite Chunks can be farmed from the big-boned, chunky Gyrm at the Doors of Pharros.
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(The use of Homeward Bones, Homeward, or if you are further in the game, the Aged Feather, come recommended for speeding up this process). Kill the Great Basilisk to obtain 3 Large Titanite Shards every time you kill him. ( Flying Feline Boots or Silvercat Ring is highly recommended). Starting from the first bonfire, go left and jump down on the mushrooms attached to the wall on the right inside the cave. An additional method preferred by some is by farming the Great Basilisk in Huntsman's Copse. Stone Trader Chloanne also stocks ten of them after you clear Iron Keep, and an unlimited number once you have cleared Drangleic Castle. If the player retrieves the Dull Ember and gives it to Steady Hand McDuff, he will then sell an unlimited number of Large Titanite Shards for 2,500 souls apiece. Some other creatures are also known to carry them around are the Iron Keep's Ironclads and the Black Gulch's Coal Tars.
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Titanite Shards can be looted from the large, green Steelworker Undead at lower Earthen Peak, as well from as the peasant villagers in upper Brightstone Cove Tseldora.As always when farming for drops, remember at least to equip your Covetous Gold Serpent Ring-maybe also a Traveling Merchant Hat, Jester's Cap, or Prisoner's Hood-and to use Rusted Coins or Watchdragon Parma if you can. Here is a list of areas and enemies which you can farm in order to obtain standard Titanite upgrade ores. Titanite Farming in Dark Souls 2 is covered on this page.
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